Firming COFs up takes Michael reaction catalysis forward

Jiang's team took this covalent organic framework and modified it to make it more stable © NPG Firming COFs up takes Michael reaction catalysis forward
	Chemists stabilise hexagonal layers that form nanochannels, which help speed up conversions

see

http://www.rsc.org/chemistryworld/2015/09/firming-cofs-takes-michael-reaction-catalysis-forward

By making formerly fragile covalent organic frameworks (COFs) resistant to harsh conditions, researchers in Japan have created what they think could be a powerful new catalyst concept. Donglin Jiang’s team at the National Institutes of Natural Sciences in Okazaki have already used their chiral COFs to enable selective and high-yielding Michael reactions with low-reactivity ketones. They believe theirs is the first example of a heterogeneous catalyst based on a crystalline porous material used in this reaction.

Dongling
 jiang
Tel: +81-564-59-5520

Fax: +81-564-59-5520

jiang@ims.ac.jp

Institute for Molecular Science, National Institutes of Natural Science

Sokendai (Graduate University for Advanced Studies)

5-1 Higashiyama, Myodaiji, Okazaki 444-8787, Japan

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