Aqueous-phase selective hydrogenation of phenol to cyclohexanone over soluble Pd nanoparticles
Green Chem., 2014, Advance Article
DOI: 10.1039/C3GC42408A, Paper
DOI: 10.1039/C3GC42408A, Paper
Jing-Fang Zhu, Guo-Hong Tao, Hang-Yu Liu, Ling He, Qian-Hui Sun, Hai-Chao Liu
The water-soluble Pd nanoparticles are highly-efficient catalysts for the selective hydrogenation of phenol to cyclohexanone in water under mild conditions.
Corresponding authors
a
College of Chemistry, Sichuan University, Chengdu 610064, China
b
College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
c
Kunming Sino-Platinum Metals Catalyst Co., Ltd., Kunming 650101, China
The water-soluble Pd nanoparticles are highly-efficient catalysts for the selective hydrogenation of phenol to cyclohexanone in water under mild conditions.
The water-soluble metal nanoparticles (NPs) stabilized by poly(N-vinyl-2-pyrrolidone) (PVP) were prepared and examined as catalysts for the one-step selective hydrogenation of phenol to cyclohexanone in water. More than 99% conversion of phenol and selectivity to cyclohexanone was obtained at 90 °C and 1 atm H2 for 16 h over “soluble” Pd NPs that were reduced by NaBH4and stabilized by PVP. These Pd NPs were stable, and no leaching or aggregation was detected after five successive runs, showing their advantage for catalyzing the efficient synthesis of cyclohexanone via the one-step selective hydrogenation of phenol under mild conditions.
