Organic Synthesis International: Bulletin of the Chemical Society of Ethiopia

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Federal Democratic Republic of Ethiopia

የኢትዮጵያ ፌዴራላዊ ዲሞክራሲያዊ
ሪፐብሊክ
ye-Ītyōṗṗyā Fēdēralāwī Dīmōkrāsīyāwī
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Coins of the Axumite king Endybis, 227–235 AD, at the British Museum. The inscriptions in Ancient Greek read "AΧWMITW BACIΛEYC" ("King of Axum") and "ΕΝΔΥΒΙC ΒΑCΙΛΕΥC" ("King Endybis").

Mountain nyalas in Nechisar National Park, one of several wildlife reserves in Ethiopia.

EXAMPLE

Journal Home > Vol 29, No 1 (2015) >

Regioselective iodination of aryl amines using 1,4-dibenzyl-1,4-diazoniabicyclo [2.2.2] octane dichloroiodate in solution and under solvent-free conditions

M. Alikarami, S. Nazarzadeh, M. Soleiman-Beigi

Abstract

1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]octane dichloroiodate is an efficient and regioselective reagent for iodination of aryl amines. A wide variety of aryl amines in reaction with this reagent afforded regioselectively iodinated products. The iodination reaction can be carried out in solution or under solvent-free condition at room temperature.

KEY WORDS: Regioselective iodination, Aryl amines, 1,4-Dibenzyl-1,4-diazoniabicyclo [2.2.2] octane dichloroiodate, Solvent-free conditions

Bull. Chem. Soc. Ethiop. 2015, 29(1), 157-162

DOI: http://dx.doi.org/10.4314/bcse.v29i1.15